Hard-extracted reserves, unconventional hydrocarbon sources
| Article # 35_2022 | submitted on 09/30/2022 displayed on website on 10/14/2022 |
| 18 p. | Portnyagin A.S., Kalacheva L.P., Ivanova I.K. |
| Investigation of the natural gas hydrates formation in the systems "stratum water - porous medium - polymer solution" according to the data of differential thermal analysis | |
| The article presents the results of studies of thermodynamic and kinetic characteristics of the natural gas hydrates formation in the systems "stratum water - porous medium - polymer solution". Commercially available polymer samples were used in the experiments: polyacrylamide, sodium carboxymethyl cellulose and polyethylene glycol. A solution of calcium chloride with a concentration of 400 g/l served as a model of stratum water, and quartz monodispersed sand was used as a porous medium. It has been established that the calcium chloride solution has a significant effect on the process of the natural gas hydrates formation. It is shown that in all studied systems, except for the models containing the sodium carboxymethyl cellulose solution, the addition of the calcium chloride solution leads to an increase of the supercooling degree of these systems, and there is a direct dependence between the supercooling degree and the concentration of the calcium chloride. The calculation of the kinetic parameters of the hydrate formation in the studied systems showed that the degree of water conversion into hydrate and the rate of hydrate formation are significantly reduced even at low concentrations of calcium chloride. Keywords: natural gas hydrates, polymer solutions, porous media, calcium chloride solution. |
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| article citation | Portnyagin A.S., Kalacheva L.P., Ivanova I.K. Izuchenie protsessov obrazovaniya gidratov prirodnogo gaza v sistemakh «plastovaya voda - poristaya sreda - rastvor polimera» po dannym differentsial'nogo termicheskogo analiza [Investigation of the natural gas hydrates formation in the systems "stratum water - porous medium - polymer solution" according to the data of differential thermal analysis]. Neftegazovaya Geologiya. Teoriya I Praktika, 2022, vol. 17, no. 4, available at: http://www.ngtp.ru/rub/2022/35_2022.html |
| DOI | https://doi.org/10.17353/2070-5379/35_2022 |
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Portnyagin A.S., Fedorova A.F., Shits E.Yu., Shilova Yu.E. Izuchenie svoystv polimernykh rastvorov i effektivnosti vytesneniya imi nefti v spetsificheskikh usloviyakh mestorozhdeniy Yugo-Zapadnoy Yakutii [Study of the properties of polymer solutions and the efficiency of oil displacement by them in the specific conditions of the fields of South-Western Yakutia]. Nauka i obrazovanie, 2013, no. 2(70), pp. 46-50.
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Shits E. Yu., Fedorova A.F., Portnyagin A.S. Eksperimental'noe opredelenie vliyaniya zakachki rastvora PPD na kollektorskie svoystva produktivnykh gorizontov Irelyakhskogo GNM [Experimental determination of the effect of injection of the reservoir pressure fluid on the reservoir properties of the productive levels of the Irelyakh GOF]. Nauka i obrazovanie, 2006, no. 1, pp. 44-48.
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Singh A., Suri A. Enhanced hydrate inhibition using protein synergists with kinetic hydrate inhibitors. Energy & Fuels, 2022, no. 36(17), pp. 10395-10404. DOI: https://doi.org/10.1021/acs.energyfuels.2c02027
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Tian Y., Li Y., An H., Ren J., Su J. Kinetics of methane hydrate formation in an aqueous solution with and without kinetic promoter (SDS) by spray reactor. Journal of Chemistry, 2017, vol. 5208915, 5 p. DOI: https://doi.org/10.1155/2017/5208915
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Troitskiy V.M., Grigor'ev B.A., Rassokhin S.G., Sokolov A.F., Kovalev A.L., Korchazhkina I.Yu., Fomin E.L., Mizin A.V., Van'kov V.P. Primenenie metodov fizicheskogo i matematicheskogo modelirovaniya dlya otsenki effektivnosti ispol'zovaniya tekhnologii vodogazovogo vozdeystviya na Chayandinskom neftegazokondensatnom mestorozhdenii [Application of physical and mathematical modeling methods to assess the effectiveness of the use of water-gas treatment technology at the Chayanda oil and gas condensate field]. Nauchno-tekhnicheskiy sbornik «Vesti gazovoy nauki», 2018, no. 5(37), pp. 140-155.
Wang R., Sun H., Shi X., Xu X., Zhang L., Zhang Z. Fundamental investigation of the effects of modified starch, carboxymethylcellulose sodium, and xanthan gum on hydrate formation under different driving forces. Energies, 2019, no.12, pp. 20-26. DOI: https://doi.org/10.3390/en12102026
Zaporozhets E.P., Shostak N.A. Teoreticheskie aspekty kinetiki gazovykh gidratov [Theoretical aspects of the kinetics of gas hydrates]. Zapiski Gornogo instituta, 2014, vol. 210, pp. 11-20.
Aregbe A.G., Sun B., Chen L. Methane hydrate dissociation conditions in high-concentration NaCl/KCl/CaCl2 aqueous solution: experiment and correlation. Journal of Chemical & Engineering Data, 2019, no. 64(7), pp. 2929-2939. DOI: https://doi.org/10.1021/acs.jced.8b01173
Chuvilin E.M., Gur'eva O.M. Eksperimental'noe izuchenie obrazovaniya gidratov SO2 v porovom prostranstve promerzayushchikh i merzlykh porod [Experimental study of the formation of CO2 hydrates in the pore space of freezing and frozen rocks]. Kriosfera Zemli, 2009, vol. XIII, no.3, pp. 70-79.
Chuvilin E.M., Perlova E.V., Makhonina N.A., Yakushev V.S. Fazovye perekhody vody v gazonasyshchennykh gruntakh [Phase transitions of water in gas-saturated soils]. Geologiya i geofizika, 2002, vol. 43, no.7, pp. 685-693.
Dzubaev S.K., Utegaliev S.A., Gazizov A.Sh., Gazizov A.A. Povyshenie nefteotdachi plastov, nasyshchennykh vysokomineralizovannymi plastovymi vodami [Enhanced oil recovery from formations saturated with highly mineralized formation waters]. Vestnik UdGU, 2005, no. 11, pp. 197-210.
Fedorova A.F., Portnyagin A.S. Osobennosti vzaimodeystviya vysokomineralizovannoy plastovoy vody Irelyakhskogo GNM s rastvorami polimerov [Features of the interaction of highly mineralized formation water of the Irelyakh GOF with polymer solutions]. Voda: khimiya i ekologiya, 2011, no. 12(42), pp. 94-97.
Fedorova A.F., Portnyagin A.S. Otsenka effektivnosti primeneniya polimernogo zavodneniya na neftyanykh mestorozhdeniyakh Yugo-Zapadnoy Yakutii [Evaluation of the effectiveness of polymer flooding in the oil fields of Southwestern Yakutia]. Tekhnicheskie nauki - ot teorii k praktike, 2013, no. 17(1), pp. 97-101.
Filimonova I.V., Eder L.V., Nemov V.Yu., Provornaya I.V. Prognoz dobychi nefti v regionakh Vostochnoy Sibiri i Respublike Sakha (Yakutiya) [Forecast of oil production in the regions of Eastern Siberia and the Republic of Sakha (Yakutia)]. Burenie i neft', 2019, no. 7(8), pp. 9-19.
General'naya skhema razvitiya neftyanoy otrasli Rossiyskoy Federatsii na period do 2020 goda: Prikaz Ministerstva energetiki RF ot 6 iyunya 2011 goda №212 [General scheme for the development of the oil industry of the Russian Federation for the period up to 2020]. Ministerstvo Energetiki Rossiyskoy Federatsii. - https://policy.asiapacificenergy.org/sites/default/files/General%20Scheme%20for%20the%20Development%20of%20Gas%20Industry%20until%202030%20%28RU%29.pdf
Gupta P., Sangwai J.S. Formation and dissociation kinetics of methane hydrate in aqueous oilfield polymer solutions (polyacrylamide, xanthan gum, and guar gum) and their performance evaluation as low-dosage kinetic hydrate inhibitors (LDHI). Energy & Fuels, 2019, no. 33(7), pp. 6335-6349. DOI: https://doi.org/10.1021/acs.energyfuels.9b01204
Istomin V.A., Fedulov D.M., Minakov I.I., Kvon V.G., Burakova S.V. Preduprezhdenie gidratoobrazovaniya v prizaboynoy zone plasta pri vysokoy mineralizatsii ostatochnoy vody v kollektore [Prevention of hydrate formation in the bottomhole formation zone with high salinity of residual water in the reservoir]. Nauchno-tekhnicheskiy sbornik «Vesti gazovoy nauki» 2013, no. 4(15), pp. 15-21.
Istomin V.A., Yakushev V.S. Gazovye gidraty v prirodnykh usloviyakh [Gas hydrates in natural conditions]. Moscow: Nedra, 1992, 236 p.
Jokandan E.F., Naeiji P., Varaminian F. The synergism of the binary and ternary solutions of polyethylene glycol, polyacrylamide and Hydroxyethyl cellulose to methane hydrate kinetic inhibitor. Journal of Natural Gas Science and Engineering, 2016, vol. 29, pp. 15-20. DOI: https://doi.org/10.1016/j.jngse.2015.12.016
Kalacheva L.P., Ivanova I.K., Portnyagin A.S. Equilibrium conditions of the natural gas hydrates formation in the pore space of dispersed rocks. IOP Conference Series: Earth and Environmental Science, 2021, vol. 666, no. 4, pp. 042062. DOI: https://doi.org/10.1088/1755-1315/666/4/042062
Kolotushenko L.D., Malinin A.V., Rudakovskaya S.Yu. Izuchenie produktivnykh otlozheniy vendskogo terrigennogo kompleksa na yugo-zapade Yakutii yaderno-magnitnymi metodami [Study of Vendian terrigenous productive accumulations in the south-west of Yakutia by nuclear magnetic methods]. Karotazhnik, 2014, no. 2(236), pp. 18-34.
Linga P., Daraboina N., Ripmeester J.A., Englezos P. Enhanced rate of gas hydrate formation in a fixed bed column filled with sand compared to a stirred vessel. Chemical Engineering Science, 2012, vol. 68, pp. 617-623.
Manakov A.Yu., Pen'kov N.V., Rodionova T.V., Nesterov A.N., Fesenko E.E. Kinetika protsessov obrazovaniya i dissotsiatsii gazovykh gidratov [Kinetics of formation and dissociation of gas hydrates]. Uspekhi khimii, 2017, vol. 86, no. 9, pp. 845-869. DOI: https://doi.org/10.1070/RCR4720
Mech D., Sangwai J.S. Effect of molecular weight of polyethylene glycol (PEG), a hydrate inhibitive water-based drilling fluid additive, on the formation and dissociation kinetics of methane hydrate. Journal of Natural Gas Science and Engineering, 2016, vol. 35, part B, pp. 1441-1452. DOI: https://doi.org/10.1016/j.jngse.2016.06.020
Medvedev V.I., Gushchin P.A., Yakushev V.S., Semenov A.P. Issledovanie vliyaniya stepeni pereokhlazhdeniya pri obrazovanii gidratov metan-propanovoy gazovoy smesi na ravnovesnye usloviya ikh razlozheniya [Investigation of the influence of the degree of supercooling during the formation of methane-propane gas mixture hydrates on the equilibrium conditions of their decomposition]. Khimiya i tekhnologiya topliv i masel, 2015, no. 5(591), pp. 30-36.
Perrin A., Musa O.M., Steed J.W. The chemistry of low dosage clathrate hydrate inhibitors. Chemical society reviews, 2013, no. 42(5), pp. 1996-2015. DOI: https://doi.org/10.1039/C2CS35340G
Portnyagin A.S., Fedorova A.F., Shits E.Yu., Shilova Yu.E. Izuchenie svoystv polimernykh rastvorov i effektivnosti vytesneniya imi nefti v spetsificheskikh usloviyakh mestorozhdeniy Yugo-Zapadnoy Yakutii [Study of the properties of polymer solutions and the efficiency of oil displacement by them in the specific conditions of the fields of South-Western Yakutia]. Nauka i obrazovanie, 2013, no. 2(70), pp. 46-50.
Safronov A.F. Geologiya nefti i gaza [Geology of oil and gas]. Yakutsk: Yakutskiy filial Izd-va SO RAN, 2000, 166 p.
Shits E. Yu., Fedorova A.F., Portnyagin A.S. Eksperimental'noe opredelenie vliyaniya zakachki rastvora PPD na kollektorskie svoystva produktivnykh gorizontov Irelyakhskogo GNM [Experimental determination of the effect of injection of the reservoir pressure fluid on the reservoir properties of the productive levels of the Irelyakh GOF]. Nauka i obrazovanie, 2006, no. 1, pp. 44-48.
Shostak N.A., Zaporozhets E.P. Opredelenie effektivnosti khimicheskikh reagentov dlya preduprezhdeniya obrazovaniya i likvidatsii gazovykh gidratov [Determination of the effectiveness of chemical reagents to prevent the formation and elimination of gas hydrates]. Zhurnal neorganicheskoy khimii, 2020, no. 2, pp. 230-236.
Singh A., Suri A. Enhanced hydrate inhibition using protein synergists with kinetic hydrate inhibitors. Energy & Fuels, 2022, no. 36(17), pp. 10395-10404. DOI: https://doi.org/10.1021/acs.energyfuels.2c02027
Slyusarev N.I. Tekhnologiya i tekhnika povysheniya nefteotdachi plastov [Technology and technique of enhanced oil recovery]. Uchebnoe posobie. St. Petersburg: Izd-vo SPGI, 2003, 78 p.
Tian Y., Li Y., An H., Ren J., Su J. Kinetics of methane hydrate formation in an aqueous solution with and without kinetic promoter (SDS) by spray reactor. Journal of Chemistry, 2017, vol. 5208915, 5 p. DOI: https://doi.org/10.1155/2017/5208915
Toma A., Sayuk B., Abirov Zh., Mazbaev E. Polimernoe zavodnenie dlya uvelicheniya nefteotdachi na mestorozhdeniyakh legkoy i tyazheloy nefti neft [Polymer flooding for enhanced oil recovery in light and heavy oil fields]. Territoriya «NEFTEGAZ», 2017, no. 7(8), pp. 58-67.
Troitskiy V.M., Grigor'ev B.A., Rassokhin S.G., Sokolov A.F., Kovalev A.L., Korchazhkina I.Yu., Fomin E.L., Mizin A.V., Van'kov V.P. Primenenie metodov fizicheskogo i matematicheskogo modelirovaniya dlya otsenki effektivnosti ispol'zovaniya tekhnologii vodogazovogo vozdeystviya na Chayandinskom neftegazokondensatnom mestorozhdenii [Application of physical and mathematical modeling methods to assess the effectiveness of the use of water-gas treatment technology at the Chayanda oil and gas condensate field]. Nauchno-tekhnicheskiy sbornik «Vesti gazovoy nauki», 2018, no. 5(37), pp. 140-155.
Wang R., Sun H., Shi X., Xu X., Zhang L., Zhang Z. Fundamental investigation of the effects of modified starch, carboxymethylcellulose sodium, and xanthan gum on hydrate formation under different driving forces. Energies, 2019, no.12, pp. 20-26. DOI: https://doi.org/10.3390/en12102026
Zaporozhets E.P., Shostak N.A. Teoreticheskie aspekty kinetiki gazovykh gidratov [Theoretical aspects of the kinetics of gas hydrates]. Zapiski Gornogo instituta, 2014, vol. 210, pp. 11-20.