Geochemical research
| Article # 9_2024 | submitted on 03/11/2024 displayed on website on 04/17/2024 |
| 19 p. | Sotnich I.S. , Kostyreva E.A. |
| Features of phenanthrenes distribution in aquagen organic matter Bazhenov Formation, Western Siberia | |
| The features of the phenanthrene distribution in the Bazhenov Formation in the southeast of Western Siberia are considered. It has been shown that with increasing maturity of organic matter, the total content of phenanthrene in bitumens increases, and the concentrations of mono-, di- and trimethyl-substituted homologues among them increase. It has been established that the modified phenanthrene parameter (PP-1mod=(1MF+9MF)/(2MF+3MF)), phenanthrene index (PI=2MF/F), ratios 1,1,7, can be used as the main indicators of the maturity of organic matter. 8-tetramethyl-1,2,3,4-tetrahydrophenanthrene/1,7,8-trimethylphenanthrene, 9MF/1MF, 9MF/F and 1MF/F, however, the influence of primary migration processes in transformed organic matter on them should be taken into account. Keywords: organic matter, bitumen, phenanthrene, primary migration process, Bazhenov Formation, Western Siberia. |
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| article citation | Sotnich I.S., Kostyreva E.A. Osobennosti raspredeleniya fenantrenov v akvagennom organicheskom veshchestve bazhenovskoy svity Zapadnoy Sibiri [Features of phenanthrenes distribution in aquagen organic matter Bazhenov Formation, Western Siberia]. Neftegazovaya Geologiya. Teoriya I Praktika, 2024, vol. 19, no. 2, available at: https://www.ngtp.ru/rub/2024/9_2024.html. EDN: NOAPCK |
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Kostyreva E.A., Sotnich I.S. Geokhimiya organicheskogo veshchestva bazhenovskoy svity severa Khanteyskoy anteklizy [Geochemistry of organic matter of the Bazhenov Formation in the north of the Khantei anteclise]. Geologiya i geofizika, 2017, vol. 58, no. 3-4, pp. 533-543. (In Russ.). DOI: 10.15372/GiG20170316
Radke M. Application of aromatic compounds as maturity indicators in source rocks and crude oils. Marine and Petroleum Geology, 1988, vol. 5, pp. 224-236. DOI: 10.1016/0264-8172(88)90003-7
Radke M., Welte D.H., Willsch H. Maturity parameters based on aromatic hydrocarbons: Influence of the organic matter type. Organic Geochemistry, 1986, vol. 10 (1-3), pp. 51-63. DOI: 10.1016/0146-6380(86)90008-2
Radke M., Willsch H., Leuthaeuser D., Teichmuller M. Aromatic components of coal: relation of distribution pattern to rank. Geochimica et Cosmochimica Acta, 1982, vol. 46, pp. 1831-1848. DOI: 10.1016/0016-7037(82)90122-3
Ryzhkova S.V., Zamiraylova A.G., Kostyreva E.A., Sotnich I.S., Fomin M.A., Eder V.G. Kharakteristika produktivnogo intervala bazhenovskoy svity v yugo-vostochnykh rayonakh Zapadnoy Sibiri (na primere Zapadno-Kvenzerskoy ploshchadi) [Characterization of Bazhenov Formation productive interval: a case study of West-Kvenzer area, southeastern Western Siberia]. Neftegazovaya Geologiya. Teoriya I Praktika, 2022, vol. 17, no. 4, available at: http://www.ngtp.ru/rub/2022/34_2022.html (In Russ.). DOI: 10.17353/2070-5379/34_2022
Sotnich I.S., Kostyreva E.A. Aromaticheskie soedineniya v bitumoidakh bazhenovskoy svity severa Khanteyskoy gemianteklizy [Aromatic compounds in bitumens of the Bazhenov Formation in the north of the Khantei hemianteclise]. Georesursy, 2021, vol. 23, no. 1, pp. 42-51. (In Russ.).
Sotnich I.S., Kostyreva E.A., Rodyakin S.V., Ryzhkova S.V., Kontorovich A.E. Differentsiatsiya bitumoidov bazhenovskoy svity Severo-Surgutskogo rayona v khode generatsii i migratsii [Differentiation of bitumens of the Bazhenov Formation of the North Surgut region during generation and migration]. Geologiya i geofizika, 2023, vol. 64, no. 12, pp. 1732-1741. (In Russ.). DOI: 10.15372/GiG2023145
Szczerba M., Rospondek M.J. Controls on distributions of methylphenanthrenes in sedimentary rock extracts: Critical evaluation of existing geochemical data from molecular modelling. Organic Geochemistry, 2010, vol. 41, pp. 1297-1311. DOI: 10.1016/j.orggeochem.2010.09.009
Zamiraylova A.G., Kostyreva E.A., Eder V.G., Ryzhkova S.V., Sotnich I.S. Litologo-geokhimicheskaya kharakteristika georgievskoy, bazhenovskoy i kulomzinskoy svit na Archinskoy ploshchadi (Nyurol'skaya vpadina, Tomskaya oblast') [Lithological and geochemical characteristics of the Georgiev, Bazhenov and Kulomzin Formations in the Archin area (Nyurol Depression, Tomsk region)]. Geologiya nefti i gaza, 2019, no. 3, pp. 99-113. (In Russ.). DOI: 10.31087/0016-7894-2019-3-99-113
Zhil'tsova A.A., Isaev V.I., Korzhov Yu.V. Vertikal'naya geokhimicheskaya zonal'nost' neftegazonosnykh kompleksov (na primere Rogozhnikovskogo i Severo-Rogozhnikovskogo mestorozhdeniy) [Vertical geochemical zoning of oil and gas complexes (on the example of the Rogozhnikov and Severo-Rogozhnikov fields)]. Izvestiya Tomskogo politekhnicheskogo universiteta, 2013, vol. 322, no. 1, pp. 69-82. (In Russ.).
Budzinski H., Garrigues Ph., Connan J., Devillers J., Domine D., Radke M., Oudin J.L. Alkylated phenanthrene distributions as maturity and origin indicators in crude oils and rock extracts. Geochimica et Cosmochimica Acta, 1995, vol. 59 (10), pp. 2043-2056. DOI: 10.1016/0016-7037(95)00125-5
Burdel'naya N.S., Bushnev D.A. Novyy pokazatel' zrelosti v organicheskom veshchestve domanikovykh otlozheniy [A new indicator of maturity in the organic matter of Domanik Formation]. Geologiya i geofizika, 2021, vol. 62, no. 2, pp. 187-196. (In Russ.).
Cassini F., Gallango O., Talukdar S., Vallejos C., Ehrmann U. Methylphenanthrene maturity index of marine source rock extracts and crude oils from the Maracaibo Basin. Organic Geochemistry, 1988, vol. 1-3, pp. 73-89. DOI: 10.1016/0146-6380(88)90027-7
Chakhmakhchev A.V., Chakhmakhchev V.A. Aromaticheskie sernistye soedineniya kak pokazateli termicheskoy zrelosti uglevodorodnykh sistem [Aromatic sulfur compounds as indicators of the thermal maturity of hydrocarbon systems]. Geokhimiya, 1995, no. 11, pp. 1656-1669. (In Russ.).
Chakhmakhchev V.A. Uglevodorody- geokhimicheskie pokazateli nefte- i gazonosnosti nedr [Hydrocarbons - geochemical indicators of oil and gas content of the subsoil]. Geokhimiya, 1989, no. 8, pp. 1108-1119. (In Russ.).
Dolzhenko K.V., Fomin A.N. Informativnost' fenantrenovykh pokazateley zrelosti organicheskogo veshchestva v pozdnem mezokatageneze i apokatageneze (na primere sverkhglubokoy skvazhiny Srednevilyuskaya-27, Vostochnaya Sibir') [Informativeness of phenanthrene indicators of maturity of organic matter in late mesocatagenesis and apocatagenesis (using the example of the ultra-deep well Srednevilyuy-27, Eastern Siberia)]. Geokhimiya, 2022, vol. 67, no. 1, pp. 37-46. (In Russ.).
Eder V.G., Ryzhkova S.V., Dzyuba O.S., Zamiraylova A.G. Litostratigrafiya i obstanovki sedimentatsii bazhenovskoy svity (Zapadnaya Sibir') v tsentral'nom, yugo-vostochnom i severnykh rayonakh ee rasprostraneniya [Lithostratigraphy and sedimentation conditions of the Bazhenov Formation (Western Siberia) in the central, southeastern and northern regions of its distribution]. Stratigrafiya. Geologicheskaya korrelyatsiya, 2022, vol. 30, no. 5, pp. 46-74. (In Russ.). DOI: 10.31857/S0869592X22050027
Fomin A.N. Katagenez organicheskogo veshchestva i neftegazonosnost' mezozoyskikh i paleozoyskikh otlozheniy Zapadno-Sibirskogo megabasseyna [Catagenesis of organic matter and oil and gas potential of Mesozoic and Paleozoic strata of the West Siberian megabasin]. Novosibirsk: INGG SO RAN, 2011, 331 p. (In Russ.).
Goncharov I.V., Samoylenko V.V., Oblasov N.V., Fadeeva S.V. Catagenesis of organic matter of rocks of the Bazhenov Formation in the southeast of Western Siberia (Tomsk region) [Katagenez organicheskogo veshchestva porod bazhenovskoy svity yugo-vostoka Zapadnoy Sibiri (Tomskaya oblast')]. Neftyanoe khozyaystvo, 2013, no. 10, pp. 32-37. (In Russ.).
Kashirtsev V.A., Parfenova T.M., Golovko A.K., Nikitenko B.L., Zueva I.N., Chalaya O.N. Biomarkery-fenantreny v organicheskom veshchestve dokembriyskikh i fanerozoyskikh otlozheniy i v neftyakh Sibirskoy platformy [Biomarkers-phenanthrene in organic matter of Precambrian and Phanerozoic strata and in oils of the Siberian platform]. Geologiya i geofizika, 2018, vol. 59, no. 10, pp. 1720-1729.
Kolesnikov A.Yu., Naydenov O.V., Matveeva I.A. Reliktovye politsiklicheskie aromaticheskie uglevodorody kak pokazateli usloviy genezisa neftey [Relict polycyclic aromatic hydrocarbons as indicators of the genesis of oils conditions]. Neftekhimiya, 1991, vol. 31, no. 6, pp. 723-736. (In Russ.).
Kontorovich A.E., Kontorovich V.A., Ryzhkova S.V., Shurygin B.N., Vakulenko L.G., Gaydeburova E.A., Danilova V.P., Kazanenkov V.A., Kim N.S., Kostyreva E.A., Moskvin V.I., Yan P.A. Paleogeografiya Zapadno-Sibirskogo osadochnogo basseyna v yurskom periode [Paleogeography of the West Siberian sedimentary basin in the Jurassic period]. Geologiya i geofizika, 2013, vol. 54, no. 8, pp. 972-1012. (In Russ.).
Kontorovich A.E., Kostyreva E.A., Rodyakin S.V., Sotnich I.S., Yan P.A. Geokhimiya bitumoidov bazhenovskoy svity [Geochemistry of bitumens of the Bazhenov Formation]. Geologiya nefti i gaza, 2018, no. 2, pp. 79-88. (In Russ.).
Kontorovich A.E., Melenevskiy V.N., Ivanova E.N., Fomin A.N. Fenantreny, aromaticheskie sterany i dibenzotiofeny v yurskikh otlozheniyakh Zapadno-Sibirskogo neftegazonosnogo basseyna i ikh znachenie dlya organicheskoy geokhimii [Phenanthrene, aromatic steranes and dibenzothiophenes in Jurassic strata of the West Siberian oil and gas basin and their significance for organic geochemistry]. Geologiya i geofizika, 2004, vol. 45, no. 7, pp. 873-883. (In Russ.).
Kostyreva E.A., Sotnich I.S. Geokhimiya organicheskogo veshchestva bazhenovskoy svity severa Khanteyskoy anteklizy [Geochemistry of organic matter of the Bazhenov Formation in the north of the Khantei anteclise]. Geologiya i geofizika, 2017, vol. 58, no. 3-4, pp. 533-543. (In Russ.). DOI: 10.15372/GiG20170316
Radke M. Application of aromatic compounds as maturity indicators in source rocks and crude oils. Marine and Petroleum Geology, 1988, vol. 5, pp. 224-236. DOI: 10.1016/0264-8172(88)90003-7
Radke M., Welte D.H., Willsch H. Maturity parameters based on aromatic hydrocarbons: Influence of the organic matter type. Organic Geochemistry, 1986, vol. 10 (1-3), pp. 51-63. DOI: 10.1016/0146-6380(86)90008-2
Radke M., Willsch H., Leuthaeuser D., Teichmuller M. Aromatic components of coal: relation of distribution pattern to rank. Geochimica et Cosmochimica Acta, 1982, vol. 46, pp. 1831-1848. DOI: 10.1016/0016-7037(82)90122-3
Ryzhkova S.V., Zamiraylova A.G., Kostyreva E.A., Sotnich I.S., Fomin M.A., Eder V.G. Kharakteristika produktivnogo intervala bazhenovskoy svity v yugo-vostochnykh rayonakh Zapadnoy Sibiri (na primere Zapadno-Kvenzerskoy ploshchadi) [Characterization of Bazhenov Formation productive interval: a case study of West-Kvenzer area, southeastern Western Siberia]. Neftegazovaya Geologiya. Teoriya I Praktika, 2022, vol. 17, no. 4, available at: http://www.ngtp.ru/rub/2022/34_2022.html (In Russ.). DOI: 10.17353/2070-5379/34_2022
Sotnich I.S., Kostyreva E.A. Aromaticheskie soedineniya v bitumoidakh bazhenovskoy svity severa Khanteyskoy gemianteklizy [Aromatic compounds in bitumens of the Bazhenov Formation in the north of the Khantei hemianteclise]. Georesursy, 2021, vol. 23, no. 1, pp. 42-51. (In Russ.).
Sotnich I.S., Kostyreva E.A., Rodyakin S.V., Ryzhkova S.V., Kontorovich A.E. Differentsiatsiya bitumoidov bazhenovskoy svity Severo-Surgutskogo rayona v khode generatsii i migratsii [Differentiation of bitumens of the Bazhenov Formation of the North Surgut region during generation and migration]. Geologiya i geofizika, 2023, vol. 64, no. 12, pp. 1732-1741. (In Russ.). DOI: 10.15372/GiG2023145
Szczerba M., Rospondek M.J. Controls on distributions of methylphenanthrenes in sedimentary rock extracts: Critical evaluation of existing geochemical data from molecular modelling. Organic Geochemistry, 2010, vol. 41, pp. 1297-1311. DOI: 10.1016/j.orggeochem.2010.09.009
Zamiraylova A.G., Kostyreva E.A., Eder V.G., Ryzhkova S.V., Sotnich I.S. Litologo-geokhimicheskaya kharakteristika georgievskoy, bazhenovskoy i kulomzinskoy svit na Archinskoy ploshchadi (Nyurol'skaya vpadina, Tomskaya oblast') [Lithological and geochemical characteristics of the Georgiev, Bazhenov and Kulomzin Formations in the Archin area (Nyurol Depression, Tomsk region)]. Geologiya nefti i gaza, 2019, no. 3, pp. 99-113. (In Russ.). DOI: 10.31087/0016-7894-2019-3-99-113
Zhil'tsova A.A., Isaev V.I., Korzhov Yu.V. Vertikal'naya geokhimicheskaya zonal'nost' neftegazonosnykh kompleksov (na primere Rogozhnikovskogo i Severo-Rogozhnikovskogo mestorozhdeniy) [Vertical geochemical zoning of oil and gas complexes (on the example of the Rogozhnikov and Severo-Rogozhnikov fields)]. Izvestiya Tomskogo politekhnicheskogo universiteta, 2013, vol. 322, no. 1, pp. 69-82. (In Russ.).